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Taking the negative logarithm of both sides, From the definitions of p K a and pH, we see that this is identical to Equation 16.52 p Thus the pH at the midpoint of the titration of a weak acid is equal to the pK a of the weak acid , as indicated in part (a) in Figure 16.20 "Effect of Acid or Base Strength on the Shape of Titration Curves" for the weakest acid where we see that the midpoint for p K a = 10 occurs at pH = 10